Course sections

Thermal properties & temperature

Measurement of temperature

  • To measure the temperature of a substance, some of its physical properties should vary with temperature; they are the thermometric properties.
  • These properties could be volume, pressure, resistance etc.
  • For these physical properties, there should be some lower and upper fix points.

Mercury in glass thermometer

  • Volume of Mercury ∝ Change in temperature.
  • Lower fix point —–melting point of ice (0 ̊C)
  • Upper fix point —–boiling point of water (100 ̊C)

Sensitivity

  • It is the length of increase of the liquid per degree rise in temperature.
  • More sensitive means more noticeable expansion.
  • Sensitivity increases with decrease in diameter of the bore.

Range

It refers to the scope of temperature it can measure, or it is the minimum to maximum measurable temperature by a thermometer.

Specific heat capacity

  • Amount of energy needed to increase the temperature of one kilogram of a substance by one degree Celsius.

c = \frac{Q}{m\Delta T}

  • Q = Energy (J)
  • m = mass (Kg)
  • ΔT = change in temperature (Co or K)
  • SI unit → \frac{J}{Kg.K} or \frac{J}{Kg.^{\circ}K}

Thermal capacity (or Heat Capacity)

  • Amount of energy needed to change the temperature of a given mass of a substance by 1 ̊C.

c = \frac{E}{\Delta T}

  • SI unit is \frac{J}{K} or \frac{J}{^{\circ}C}

E = mc\Delta T

E = C\Delta T

C = mc

  • Heat capacity = mass x specific heat capacity

Phase Change:

Specific latent heat

  • Amount of energy required per unit mass to change the phase of a material.

Specific heat latent of Fusion/Liquification

  • Amount of energy needed to change the phase of one kilogram of a solid to liquid at constant temperature.

L_{f} = \frac{Q}{m}

  • SI unit is \frac{J}{kg}

Specific heat latent of a Vaporization/Condensation

  • Amount of energy needed to change the phase of one kilogram of a liquid to gas at constant temperature.

L_{v} = \frac{Q}{m}

  • SI unit is \frac{J}{kg}